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A mechanistic proposal for the protodeboronation of neat boronic acids: boronic acid mediated reaction in the solid state.

Noonan, G and Leach, AG (2015) A mechanistic proposal for the protodeboronation of neat boronic acids: boronic acid mediated reaction in the solid state. Organic and Biomolecular Chemistry, 13. pp. 2555-2560. ISSN 1477-0539

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Abstract

A combined experimental and computational study suggests that a reduction in the entropy of activation in the solid state can lead to the protodeboronation of boronic acids.

Item Type: Article
Uncontrolled Keywords: 0304 Medicinal And Biomolecular Chemistry, 0305 Organic Chemistry, 1115 Pharmacology And Pharmaceutical Sciences
Subjects: Q Science > QD Chemistry
Divisions: Pharmacy & Biomolecular Sciences
Publisher: Royal society of Chemistry
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Date Deposited: 30 Jan 2015 16:17
Last Modified: 09 Jan 2016 00:50
DOI or Identification number: 10.1039/c4ob02543a
URI: http://researchonline.ljmu.ac.uk/id/eprint/352

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