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Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

Yoshizawa, A, Feula, A, Leach, AG, Male, L and Fossey, JS (2018) Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes. Frontiers in Chemistry, 6. ISSN 2296-2646

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Abstract

Seven N,N’-palladium(II) chloride complexes, one N,N’-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N’-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN’ metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

Item Type: Article
Uncontrolled Keywords: Science & Technology; Physical Sciences; Chemistry, Multidisciplinary; Chemistry; azetidine; ligand; platinum; palladium; complex; pyrrolidine; CROSS-COUPLINGS; CATALYSIS; SECONDARY; LIGANDS; COORDINATION; PYRROLIDINES; OXALIPLATIN; CISPLATIN; PD(II)
Subjects: Q Science > QD Chemistry
Divisions: Pharmacy & Biomolecular Sciences
Publisher: Frontiers Media
Related URLs:
Date Deposited: 27 Sep 2018 08:54
Last Modified: 27 Sep 2018 09:04
DOI or Identification number: 10.3389/fchem.2018.00211
URI: http://researchonline.ljmu.ac.uk/id/eprint/9337

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