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Tatum, NJ, Yufit, DS, Cobb, SL and Coxon, CR (2015) Synthesis, Ni(II) Schiff base complexation and structural analysis of fluorinated analogs of the ligand (S)-2-[N-(N '-benzylprolyl)amino]benzophenone (BPB). JOURNAL OF FLUORINE CHEMISTRY, 173. pp. 77-83. ISSN 0022-1139
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J Fluor Chem_Revised Manuscript JAN 15.pdf - Accepted Version Available under License Creative Commons Attribution Non-commercial No Derivatives. Download (1MB) | Preview |
Abstract
Herein we report the first X-ray crystal structure of the well-known (S)-L-ala-Ni-BPB complex (1) and compare this with the X-ray crystal structures obtained for two novel fluorinated (S)-L-ala-Ni-BPB complexes (8 and 12) that contain either an S- or R-fluorine atom on the proline ring of the BPB ligand. The preparation of complexes 8 and 12 has been enabled by the synthesis of two new fluorinated BPB ligands (7 and 11). In this work we looked to observe structural effects that the introduction of a single fluorine atom has on the known complex 1. Arising from this, we highlight a novel fluorine – nickel interaction that may provide additional stabilisation to complex 8.
| Item Type: | Article |
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| Uncontrolled Keywords: | 0302 Inorganic Chemistry, 0305 Organic Chemistry |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Pharmacy & Biomolecular Sciences |
| Publisher: | ELSEVIER |
| Related URLs: | |
| Date Deposited: | 06 Oct 2016 09:08 |
| Last Modified: | 18 May 2022 09:55 |
| DOI or ID number: | 10.1016/j.jfluchem.2015.02.007 |
| URI: | https://researchonline.ljmu.ac.uk/id/eprint/821 |
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